6–10 Jul 2026
University of the Western Cape
Africa/Johannesburg timezone
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Synthesis, structural, and photoluminescent properties of green emitted Eu2+ doped SrAl2O4 phosphor

8 Jul 2026, 16:20
1h 20m
Great Hall ( University of the Western Cape)

Great Hall

University of the Western Cape

Poster Presentation Track A - Physics of Condensed Matter and Materials Poster Session 2

Speaker

Lethabile Masiu (Lethabile Masiu)

Description

SrAl2O4:Eu2+ is a well-known phosphor due to its strong green emission. The intense green emission makes SrAl2O4:Eu2+ an extremely interesting material for a broad range of applications, including emergency and safety lighting, anti-counterfeiting labels, roadway markings, and phosphor-coated bricks. This study investigates Eu2+-doped SrAl2O4 phosphors synthesized via the solid-state reaction method and characterized using X-ray powder diffraction (XRPD), photoluminescence (PL), and UV–Vis spectroscopy. XRPD analysis confirmed the formation of monoclinic SrAl2O4 after annealing at 1600°C. Residual SrCO3 observed at lower temperatures indicates incomplete phase formation, emphasizing the importance of high-temperature annealing to achieve phase purity and enhanced crystallinity. The effect of Eu2+ doping revealed concentration-dependent structural modifications. UV–Vis spectroscopy supported these findings, showing characteristic Eu2+ (4f–5d) absorption bands. PL results demonstrated enhanced emission intensity for samples synthesized through a two-step calcination and annealing process in a reducing Ar–5%H2 atmosphere, ensuring effective reduction of Eu3+ to Eu2+. These results highlight the importance of controlled synthesis in optimizing luminescent properties.

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Author

Lethabile Masiu (Lethabile Masiu)

Co-authors

Mart-Mari Duvenhage (University of the Free State) Mubarak Yagoub (University of Johannesburg)

Presentation materials

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