7–11 Jul 2025
University of the Witwatersrand, Johannesburg
Africa/Johannesburg timezone
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Statistical Discrimination of Uranium Ore Concentrate Using Trace Element Signatures: Developing nuclear forensic fingerprints

9 Jul 2025, 11:10
20m
Solomon Mahlangu House (University of the Witwatersrand, Johannesburg)

Solomon Mahlangu House

University of the Witwatersrand, Johannesburg

Oral Presentation Track B - Nuclear, Particle and Radiation Physics Nuclear, Particle and Radiation Physics-1

Speaker

Ms Liteboho Ntsohi (School of Physics, University of Witwatersrand, Johannesburg, South Africa)

Description

Similar to ordinary forensics, nuclear forensic science uses data and modelling to infer historical information such as origin and production processes. To do this, unique characteristics of different nuclear material that make up nuclear fingerprint must be identified. To date, very few characteristics have been identified as signatures for uranium ore and uranium ore concentrate(UOC) including the REE pattern and trace elements (geological indicators of deposit type). In this study, the concentrations of trace elements: Ti, V, Cr, Co, Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Sn, Cs, Ba, W, Pb in 9 different UOC surrogate samples collected from Botswana and Nigeria were determined using Inductively Coupled Plasma Mass Spectrometry. The compositional trace element data were subjected to an arsenal of univariate and multivariate statistical analysis techniques such as correlation analysis, one-way Analysis of Variance, Principal Component Analysis, and Hierarchical Cluster analysis to quantify the statistical significance of the differences observed and to test the potential discriminative power of individual trace elements between ores from the same region. ANOVA revealed significant differences (p<0.5) in Ti, Zn and Pb only while no significant differences (p>0.05) were observed in V, Cr, Co, Ni, Cu, Ga, Rb, Sr, Y, Zr, Sn, Cs, Ba, W. The study further found three principal components that explained 91% of the variance in the UOC samples. PC1 (V, Ti, Pb, Sn), PC2 (Cr, Cu, Zr) and PC3 (Cs, Rb, Zn), respectively. This study highlighted the potential trace elements signatures to distinguish between uranium ore from different locations.

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Primary author

Ms Liteboho Ntsohi (School of Physics, University of Witwatersrand, Johannesburg, South Africa)

Co-authors

Prof. Iyabo Usman (School of Physics, University of Witwatersrand, Johannesburg, South Africa) Dr Mistura Ajani (University of Ilesa, Osun State, Nigeria) Dr Oscar Kureba (Botswana International University of Science and Technology, Palapye, Botswana) Dr Risimati Mavunda (South African Nuclear Energy Corporation, South Africa)

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